The invention discloses a laminated polymer solar cell, which comprises a base plate, an anode layer, an anode modification layer, a first active layer, a cathode modification layer, a cathode layer and an intermediate electrode consisting of an electronic transport layer, a metal layer and a hole transport layer, wherein the intermediate electrode consists of an n-type metallic oxide electron transport layer and a p-type metallic oxide hole transport layer which are high in light transmittance. A thin layer of metal is inserted between the two metallic oxides and the effective combination ofelectrons and holes. The active layers of up and down two sub-cells of the laminated polymer solar cell are mixtures of identical or different conjugated polymers. The open circuit voltage of the laminated solar cell is the sum of the open circuit voltages of the up and down two sub-cells, so the serial connection of polymer photovoltaic cells is realized. The combined intermediated electrode structure can be wildly used in laminated devices with active layers made of conjugated polymers of different light absorption ranges, so as to well match the light absorption of the whole cell with the solar spectrum and improve the energy conversion rate.