The invention relates to silicate cement for producing advanced silicon refractory material; the cement mainly comprises tricalcium silicate, dicalcium silicate and dicalcium ferrite without Al2O3, and C3S is of high content and great fineness; theoretical mineral composition of the cement is 95 to 80 percent of C3S, 2 to 14 percent of C2S and 3 to 10 percent of C2F, as well as 1 to 2 percent of fluorite, 0 to 6 percent of calcium sulfate and 0 to 4 percent of magnesium sulfate or magnesium oxide which are added as mineralizer. The production process of the cement is that a raw material of 0.088 sieve residue less than 10 percent is designed according to the composition and prepared after mixing and grinding; then the raw material is blanked, dried and then sintered for 1 to 6 hours at 1260 to 1350 DEG C; then, the cement with median particle size D50 is equal to 2 to 10Mum is prepared by an ultrafine powder grinding device. The invention is characterized by rapid hardness, high strength, favorable adaptability to ultrafine powder and admixture, no impurity Al2O3 and so on, and the invention is suitable for the binder and mineralizer of the advance silicon refractory material.