The invention relates to a method for preparing barium titanate or strontium titanate laminated compound materials by using the electrophoretic deposition technology in water solution, which comprisesthe following steps: respectively preparing barium titanate and strontium titanate water solution suspending liquid in two vessels, adjusting the pH value after dispersing, taking a graphite electrode as an anode and a cathode, supplying voltage by direct current power supply, arranging the electrodes into the barium titanate suspending liquid, obtaining barium titanate film on the cathode afteradjusting voltage and aggradating time, naturally drying the obtained film under room temperature, arranging the electrodes with film into the strontium titanate suspending liquid, obtaining strontiumtitanate film on the cathode, naturally drying the obtained film under room temperature, and repeating the above steps then obtaining the barium titanate or strontium titanate laminated compound materials. The compound materials which is prepared by the method of the invention has the advantages of adjustable number of plies and film thickness and the like, and the method of the invention has theadvantages that the operation is simple, the production cost is reduced by without using organic solvent, which is applicable to industrialized production.