The invention relates to aqueous solution with fine water mist fire extinguishment additive, with the quality percentage of all components as below: ammonium chloride 0 percent to 1 percent, polyvinyl alcohol 0 percent to 1 percent, sodium acetate 0 percent to 0.5 percent, surface active agent 0.01 percent to 0.25 percent, urea 0 percent to 1 percent, rust preventive 0.01 percent to 0.25 percent, and the rest is water. The aqueous solution can improve the fire extinguishing efficiency of the fine water mist and effectively prevent after-combustion of inflamers; has little corrosion to equipments and instruments; basically has no pollution to fire scenes; is high-efficiency, stable and clean; the raw materials of all components are easy to be obtained; has stable performance; is basically nontoxic and low in cost; and has low consumption.