The invention relates to titanium dioxide with high water dispersibility and a coating process, belonging to the chemical industry field, which solves the technical problem that titanium dioxide which is produced by a current process has lower dispersibility. The coating process of titanium dioxide with high water dispersibility of the invention comprises the steps of beating, silicon coating, aluminum coating, scouring, drying and disintegrating and the like, wherein sodium aluminate solution is used to conduct coating in the aluminum coating step, and sodium silicate solution is used to conduct coating in the silicon coating step, wherein the molar ratio of sodium aluminate solution usage which is calculated with A1 2 O3 and sodium silicate usage which is calculated with SiO 2 is 1:4. The process of the invention can be used to prepare titanium dioxide with high water dispersibility, which has widespread application prospect, and the Haegeman index of titanium dioxide which is prepared can reach over 7.0 in emulsion paint.