The present invention provides a method of preparing a direct higher alcohol battery membrane electrode, characterized in that the method includes following steps: A. dispersing a catalyst and a first binder to a dispersant, obtaining slurry; B. heating the slurry 10 min-3 hours under 40-100 DEG C, then ultrasonic heating 10 mins-2hours, forming uniform slurry; C. coating the slurry on the support layer to form a membrane electrode. The method of the preparing direct higher alcohol battery membrane electrode of the invention is simple, and easy to operate, markedly improving the power densityand the stability of the fuel battery by adjusting and controlling the aggregation state of the first binder. The membrane electrode of the invention effectively improves the catalytic activity and the efficiency of the electrode, improving the catalytic activity and the utilization ratio of the catalyst of the fuel battery membrane electrode, effectively improving the performance and the stability of the battery, reducing the polarization loss of the battery, so as to improve the performance of the fuel battery.