The invention relates to a heater composite sanitary napkin and a preparation and packaging method thereof. The heater composite sanitary napkin is composed of a conventional sanitary napkin and a heater combined layer, the heater combined layer is composed of upper and lower surface layers of air-permeable layers with the same structures and materials and a middle heating substance sheet layer, the middle sheet of the air-permeable layers is melt blowing nonwoven fabric, the upper and lower layers are nonwoven fabric which is made by the composite technology; and the heating substance sheet layer is formed by mixing and pressing metal signal substance, sodium chloride and activated carbon according to the proportion. The heating sheet layer is firstly arranged in the heater combined layer which is provided with seven layers and is formed between the two pre-made air-permeable layers by hot rolling and then is fixed between an absorption layer and a mesh surface layer of the sanitary napkin by binding or hot rolling, the vacuum pumping is carried out or protective gas is introduced, the exterior thereof is packaged by an oxygen isolating thin film, and the formed package body can be stored for a long time. The reaction is activated by tearing the thin film. The product has the effects of waterproof, anti-leakage, convenient and long-term stable heating, warming uterus and reducing dysmenorrheal. The preparation method is simple and the packaging effect is good.