The invention provides a paint combination, which comprises pigments, multilevel polyvinyl alcohol ester dispersion as binding agent and/or fillings. The binding agent is prepared by the selected multi-step method which comprises: a first step for gaining polyvinyl alcohol ester dispersion; a second step for adding a monomer into the reaction mixture in solvent/pure/emulsion manner to start polyreaction again. The polyvinyl alcohol ester dispersion comprises polymeric silane and/or epoxide or a little protective colloid. The paint combination in the invention is notable for its high resistance to elements.