The invention discloses a method for separating and recovering volatile halogenated hydrocarbon compounds in the gas through a hydrophobic high crosslinking absorptive resin. The method comprises the following steps: passing the exhaust gas through an absorption column containing the hydrophobic high crosslinking absorptive resin at the flow rate of between 0.1 and 0.5m/s at normal temperature and under normal pressure after filtration and cooling; and reducing the concentration of the gas to below 0.1 percent of the inlet concentration after the absorption column; adopting 0.15 to 0.4MPa and 110 to 140 DEG C steam for desorption, and reaching the desorption rate of above 99 percent; and delaminating the desorption liquid through condensation so as to separate oil from water, and reaching the organic matter recovery rate to between 90 and 96 percent. The method has simple operation; and the resin can be used for absorption again without being dried after the resin is used for steam desorption and is regenerated. Therefore, the method greatly reduces the regeneration time, and has a good recovery effect and wide application prospect.