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CN101560388A 一种钐金属有机配合物发光材料及其合成与应用 有权

一种钐金属有机配合物发光材料及其合成与应用
摘要：
一种钐金属有机配合物发光材料及其合成与应用，涉及[Sm2(N4CC6H4COO)2(N4CHC6H4COO)2(H2O)10]配合物的制备和应用。该材料采用水热反应得到晶体。该配合物空间群为P－1(No.2)，单胞参数a＝8.4310(11)，b＝10.554(3)，c＝13.4526(16)，α＝110.1170(10)°，β＝100.521(10)°， γ＝101.802(15)°，Z＝1，单胞体积V＝1057.7(3)3。5－苯甲酸－四氮唑可增强该材料的Sm3+荧光发光。该材料用于制作荧光发光器件。
摘要（英）：

The invention discloses samarium organometallic composition luminescent materials, as well as a synthesis and an application thereof, relating to a preparation and an application of a composition [Sm2(N4 CC6 H4 COO) 2 (N4 CHC6 H4 COO) 2 (H2O) 10]. The materials adopt a hydrothermal reaction to obtain crystal. In the composition, a space group: P-1 (No.2), unit cell parameters: alpha is equal to 110.1170(10) degrees, beta is equal to 100.521(10)degrees, gamma is equal to 101.802(15)degrees, and Z is equal to 1, and unitcell volume is equal to 1057.7 (3) <3>. 5-benzoic acid-tetrazolium can strengthen Sm <3+> fluorescence luminescence of the materials. The materials are used for manufacturing a fluorescence luminescent device.

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