The invention provides a method for attaching matte transparent conductive film on a substrate, comprising the following steps: coating mixed liquor of polymer colloid micro ball and silica sol by a spin coating method on the substrate based on the principle for forming macropore molecular sieve; after removing the template of polymer colloid micro ball by co-assembling and calcining, forming a layer of silicon oxide film in regular concave and convex arrangement; using the substrate as an underlay to deposit the transparent conductive oxide film so as to obtain the transparent conductive filmwith concave and convex structure. The film can be used as the front electrode of the film solar cell, can increase dispersion to light, improves the utilization factor of light and improves the conversion efficiency of the solar cell as a result of light trapping function of the surface.