The invention discloses a production method of no-yellowing composite leather, which is implemented by following scheme: preparing no-yellowing resin, DMF, MEK, TOL, antioxidant and pigment into plus materials; preparing hydrolysis resistant substrate, DMF, MEK, TOL, antioxidant and pigment into a substrate; selecting proper base materials; preparing the plus material, substrate and base materialat a temperature of 160 +-20 DEG according to common dry coating method to obtain composite containing the plus material layer, substrate layer and base material layer; external surface of the plus material layer of the composite leather is printed with NOX resistant auxiliaries, then proceeding NOX resistant treatment to obtain no-yellowing composite leather of the invention. The invention proceeds uvioresistant treatment to the no-yellowing resin in the plus material and the substrate, adding anti-oxidation additives in the plus material and the substrate to reduce dosage of TOL and MEK which are easily discolored in air by oxidation, and increas dosage of DMF to improve antioxygenic property of composite leather; improving temperature of oven in process of producing leather by dry coating method, solvent is volatilized completely, yellowing caused by solvent is avoided; adding a printing process to proceed NOX resistant treatment on surface of the composite leather, which can avoidyellowing caused by NOX oxidation in air effectively.