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CN101723987A 有机发光材料4,6-二苯基-2,2′-联吡啶铂(Ⅱ)炔配合物、合成方法及应用 无效 - 撤回

  • Patent Title: 有机发光材料4,6-二苯基-2,2′-联吡啶铂(Ⅱ)炔配合物、合成方法及应用
  • Patent Title (English): Organic luminescent material 4, 6-diphenyl-2, 2'-dipyridyl platinum (II) alkyne coordination compound, synthesis method and application thereof
  • Application No.: CN200910232613.7
    Application Date: 2009-12-03
  • Publication No.: CN101723987A
    Publication Date: 2010-06-09
  • Inventor: 朱红军 , 刘睿 , 张东明 , 常进 , 李钰皓 , 肖琪 , 陈洪彬
  • Applicant: 南京工业大学
  • Applicant Address: 江苏省南京市鼓楼区新模范马路5号
  • Assignee: 南京工业大学
  • Current Assignee: 南京工业大学
  • Current Assignee Address: 江苏省南京市鼓楼区新模范马路5号
  • Main IPC: C07F15/00
  • IPC: C07F15/00 ;  C09K11/06
有机发光材料4,6-二苯基-2,2′-联吡啶铂(Ⅱ)炔配合物、合成方法及应用
Abstract:
本发明提供一种4，6-二苯基-2，2′-联吡啶铂(II)炔配合物有机发光材料、制备方法及应用。本发明以4，6-二苯基-2，2′-联吡啶铂(II)氯配合物为原料，在三异丙基胺和碘化亚铜的作用下，与末端芳炔在二氯甲烷中发生配位取代反应20至50小时，得到系列4，6-二苯基-2，2′-联吡啶铂(II)炔配合物。该类配合物可作为有机发光材料。
Abstract(English):

The invention provides a 4, 6-diphenyl-2, 2'-dipyridyl platinum (II) alkyne coordination compound organic luminescent material, preparation method and application thereof. The invention takes 4, 6-diphenyl-2, 2'-dipyridyl platinum (II) chlorine coordination compound as raw material, under the action of tri-isopropyl amine and koper iodide, the coordination compound and terminal aryne take coordination substitute reaction in dichloromethane for 20-50 hours, so as to obtain series of 4, 6-diphenyl-2, 2'-dipyridyl platinum (II) alkyne coordination compound. The coordination compound can be taken as organic luminescent material.

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