The invention belongs to the rubber field, in particular a green tire material containing amphipathic starch derivant and a preparation method thereof. The method for preparing the green tire material containing the amphipathic starch derivant comprises the following steps of: pre-dispersing fine particles of the amphipathic starch derivant in polymer emulsion to obtain the compound of the amphipathic starch derivant and the polymer, and then mixing the compound with rubber, a reinforcing agent, a coupling agent, a vulcanizer and a vulcanizing accelerator, processing by a rubber mixing mill or an internal mixer at 30-100 DEG C to obtain a co-mixture containing the amphipathic starch derivant and the rubber; vulcanizing by a vulcanizer for 20-40 min at 100-150 DEG C to obtain the green tire material containing the amphipathic starch derivant. The prepared green tire material containing the amphipathic starch derivant realizes the functionalization of rubber material, has functions of low rolling resistance, high wet skid resistance, higher antistatic performance of the material and the like. The green tire material can be used for producing rubber products such as tires.