The invention discloses novel solar covering glass with an anti-reflective film and a manufacturing method thereof. The glass comprises a glass base layer, a first porous SiO2 film coating layer and a second porous SiO2 film coating layer. The manufacturing method comprises the steps of preparing first sol and second sol; respectively spraying the first sol and the second sol on the surface of the front side of the glass base layer by adopting spray technology to plate the first porous SiO2 film coating layer and the second porous SiO2 film coating layer in turn; and performing drying and toughening treatment on the glass base layer to prepare the covering glass finished product plated with two layers of the anti-reflective films. Tests prove that the transmissivity of the covering glass finished product exceeds 95 percent in a wavelength range of between 400 and 800nm. The glass has the characteristics of simple structure, simple technical process, easy implementation and the like.