The invention discloses a treating method for efficiently catalyzing and oxidizing chlor-alkali industrial waste water. In the method, sodium hypochlorite in the chlor-alkali industrial waste water is decomposed mainly by adding a nickel oxide catalyst with an efficient surface; and simultaneously a small amount of other pollutants in the waste water is degraded. The treating method for efficiently catalyzing and oxidizing the chlor-alkali industrial waste water of the invention comprises the following step of: making sodium hypochlorite-containing alkaline waste water continuously flow through a catalytic oxidation reaction bed filled with a catalyst from the bottom to the top at an air speed of between 1.6 and 2.6 h<-1>.