An extracting apparatus includes a first flask for containing raw material and solvent for dissolving the raw material to form a solution; second flasks each disposed in a cooling bath and containing a quantity of aromatic compounds absorbent fluid; a third flask disposed in a third cooling bath; and thermometers each disposed in each of the first, second, and third cooling baths. The first flask is connected to the first one of the second flasks after removing from the first cooling bath. The second flasks are interconnected. The third flask is connected to the last one of the second flasks. The solution evaporates to flow vapors through the second flasks sequentially, vaporized aromatic compounds of the solution are absorbed by the aromatic compounds absorbent fluid, and vaporized solvent of the solution reaches the third flask to be condensed and collected therein. An extracting process is also provided.