The invention discloses double-fluid rapid hardening slurry for roadway grouting and mollisol compaction grouting, remedying the defects that a cement-sodium silicate slurry concrement body has poor durability, and the grouting process is complicated. The slurry contains fluids A and B; the fluids A and B are injected at equal volume, and the on-site operation is simple. The fluid A contains 50 percent of portland cement, 0.5-0.75 percent of inorganic sodium salt, 0.025-0.05 percent of organic alcohol early strength agent and the balance of water; and the fluid B contains 43.6-48.8 percent of coal ash, 13.9-20.05 percent of sodium silicate and the balance of water. The performances of the slurry are shown as follows: the gelation time is adjustable within the range of 36s-124s, the concrement rate is 100 percent and the early compression strength is high; moreover, the concrement body has good durability and does not crack or pulverize. Compared with the original cement-sodium silicate slurry, the grouting process is simple, the durability of the slurry concrement body is obviously improved, the sodium silicate consumption is saved and the grouting cost is greatly reduced.