The invention discloses a polyphenyl ether alloy resin material for processing a photovoltaic connector, which comprises the following components of polyphenyl ether resins, polystyrene resins, elastomers, a fire retardant, polyolefin, inorganic oxides, silicone master batch, an ultraviolet agent, a master antioxidant and an auxiliary antioxidant. In the invention, the mechanical property (the low-temperature impact property), heat resistance property, weather resistance property, insulating property and the flame retardant property of the material are improved by regulating the appropriate ratio of the components in the polyphenyl ether resin composite, and the product can meet the requirements of a PV CONNECTOR test of technischen uberwachungs-vereine (TUV), the standard of the Restriction of the use of Certain Hazardous Substances in Electrical and Electronic Equipment (ROSH) and the application requirements in the field of the photovoltaic connector.