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发明公开
CN102000610A 钨系或钼系多金属氧酸盐超分子化合物及其制备方法和应用 失效 - 权利终止

钨系或钼系多金属氧酸盐超分子化合物及其制备方法和应用
摘要：
本发明公开了一种钨系多金属氧酸盐超分子化合物及其制备方法和应用，该化合物的分子式为(BMI)2(DMDI)(PM12O40)；其中BMI为DMDI为该化合物为单斜晶系，空间群为pbcn，晶胞参数为：a＝17.895(5)，b＝18.391(5)，c＝16.676(4)，α＝β＝γ＝90。该化合物分子式中钨系多金属氧酸为化合物的基本构筑单元，通过氢键沿a轴构成一维链状(BMI)2(DMDI)(PM12O40)结构。该催化剂在催化聚合时具有可太阳光照射聚合、聚合物的Mn和PD值可随意控制和催化剂可回收循环利用等特征。
摘要（英）：

The invention discloses a tungsten series and molybdenum series polyoxometallate super molecular compound as well as a preparation method and application thereof. A molecular formula of the compound is (BMI)2(DMDI)(PM12O40), wherein BMI and DMDI are of a monoclinic system of the compound, the space group is pbcn, and the cell parameters are follows: a=17.895(5), b=18.391(5), c=16.676(4), and alpha=beta=gamma=90. In the molecular formula of the compound, tungsten series polyoxometallate is a basic construction unit of the compound and forms a one-dimensional chain (BMI)2(DMDI)(PM12O40) structure through hydrogen bonds along an a axis. The catalyst has the characteristics: in the catalytic polymerization, sunlight irradiation polymerization can be achieved, Mn and PD values of a polymer arecontrollable randomly, the catalyst can be recovered and recycled, and the like.

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