The invention relates to a composite material core used for an enhanced cable, a preparation process and the enhanced cable. The composite material core comprises an inner core and an outer layer, wherein the inner core is composed of fiber and thermosetting resin; the outer layer comprises a fiber woven pipe and thermosetting resin which are composited to form the outer layer; and the fiber woven pipe of the outer layer is a network structure which is woven by interlacing a plurality of fiber bundles. The transversal strength of the composite material core is greatly improved by the interlaced network structure, the fatigue resistance of the composite material core is greatly improved, and the service life of the composite material core and a power transmission cable is prolonged; and the problem that the composite material core is broken when the composite material core is stranded, wound and extruded by a conductor in the manufacturing process of the cable is completely avoided. Asthe fiber woven pipe is adopted by the outer layer, the flexibility of the outer layer is greatly increased by the interlaced and woven structure, thereby meeting the requirement of manufacturing composite material core with major diameter.