The invention discloses a high-temperature solar blind ultraviolet photoelectric tube and a manufacturing method thereof. The photoelectric tube comprises a core column, a molybdenum group purple glass permeable shell, a metal straight rod and a molybdenum electrode, wherein the molybdenum group purple glass permeable shell is encapsulated on the core column; the metal straight rod is arranged inthe core column; and the molybdenum electrode is connected to the metal straight rod. When the high-temperature solar blind ultraviolet photoelectric tube exhausts air, the molybdenum group purple glass permeable shell is baked at high temperature for a long time and the molybdenum electrode is treated by an electron bombardment method. The photoelectric tube has the advantages of high sensitivity, high reliability, long service life, high response speed, high temperature resistance, no response to visible light and infrared light, light weight and the like.