The invention relates to a high thermal conductivity insulation structure of a stator bar of an excess epoxy mould pressing insulation system. The stator bar is suitable for the excess epoxy mould pressing insulation system. High thermal conductivity ceramic fiber is contained in the insulation layer on the outer surface of an electromagnetic wire; and reinforcement material in position-changing pit insulation, bar insulation, a restricted area filler strip, major insulation and anti-corona material contains the high thermal conductivity ceramic fiber. The stator bar manufactured by the invention has major technical performance figures that firstly, the temperature conductivity reaches 0.5 W/mK; secondly, tg delta is smaller than 1% under normal 0.2 UN (nominal voltage); thirdly, the stator bar has no visible corona trace for 60 seconds under 1.5 UN; fourthly, the flashover voltage of the finished bar reaches 5.5 UN; and fifthly, the service life of the bar is longer than 10 h under the 3.0 UN and is longer than 1100 h under the 2.0 UN during the electric resistance aging test.