The invention discloses a method for preparing high fullerene and a special anode thereof. The anode is prepared according to the following method: filling a mixture of graphite and mixed polycyclic aromatic hydrocarbon into a hollow graphite rod so as to obtain the anode. In the mixture of the graphite and the mixed polycyclic aromatic hydrocarbon, the mass ratio of the graphite with the polycyclic aromatic hydrocarbon is 1:20. The method comprises the following steps: conducting arc discharging on the anode and cathode under the He atmosphere so as to obtain high fullerene which is at leastone of C76, C78, C84, C86 and C90. In the invention, a certain proportion of mixed polycyclic aromatic hydrocarbon is added in the graphite, so that the yield of C76 can be improved by 2-3 times, theyield of the C78 and the C84 can be improved by about 4 times, and the yield of the C86 and the C90 is improved by a certain degree.