The invention relates to a method for preparing nitrogenous graphitized hollow carbon microspheres, which relates to a method for preparing hollow carbon microspheres. The method disclosed by the invention aims to solve the technical problem that in the existing method for preparing nitrogenous graphitized hollow carbon microspheres, because a template agent is utilized, the preparation process is complicated, and the cost is increased. The method comprises the following steps: adding melamine powder and a formaldehyde solution into deionized water, and after heating for reaction, obtaining reaction liquid; then, transferring the reaction liquid into a reaction kettle, and after carrying out hydrothermal reaction on the reaction liquid, obtaining melamine resin microspheres; and putting the melamine resin microspheres into a quartz tube type furnace, and heating the melamine resin microspheres so as to split the melamine resin microspheres, thereby obtaining nitrogenous graphitized hollow carbon microspheres. The average diameter of the nitrogenous graphitized hollow carbon microspheres is 1-5 microns; and by using the method, no template agent and no catalyst are required to be added in the preparation process, the preparation process in a synthesis method is simple, the cost is low, and microspheres are easy to be performed mass production and can be used as electrode materials or carrier materials of active substances of electrodes in the fields of electrochemical super capacitors, lithium ion batteries, fuel cells and the like.