There is provided a primer composition having a curative, a solvent, and an epoxide resin; wherein the curative is capable of reacting the epoxide resin; and further wherein; (a) the curative is capable of curing a perfluoroelastomer compound having at least one cure site and a crosslinking agent or catalyst; or (b) when the curative is not capable of curing the perfluoroelastomer compound, the perfluoroelastomer comprises a crosslinking agent or catalyst capable of curing the epoxide resin. The primer composition according to the present disclosure are used to bond perfluoroelastomer compounds to substrates. Methods of bonding a perfluoroelastomer compound to a substrate and multilayered articles comprising a perfluoroelastomer, a primer layer, and a substrate are also provided.