The invention provides a porcelain tooth shade guide and a production method of colorimetric dental films of the porcelain tooth shade guide and aims at enabling the colorimetric dental films of porcelain tooth shade guide to be identical to color and gloss of dermal teeth as far as possible. The porcelain tooth shade guide comprises a plurality of colorimetric dental film assemblies, and each colorimetric dental film assembly comprises a colorimetric dental film and a color scale handle. Each colorimetric dental film is formed by a metal base and multilayer veneering porcelain which is divided into a transparent porcelain layer, an incisal porcelain layer, a body porcelain layer and two layers of masking porcelain sequentially from the surface to the inside, and the metal base is fixedly connected with one end of the color scale handle through a screw. The colorimetric dental films of the porcelain tooth shade guide are nearly identical to clinical porcelain tooth prosthesis and dermal teeth in color and gloss, and therefore the porcelain tooth shade guide is reliable in accuracy when being used for guiding clinical color selection and color matching, is obviously prior to the traditional shade guide and can thoroughly solve the problem of inaccurate color matching which puzzles dentists for many years. Each batch of colorimetric dental films are all quantized, standardized and unitized in shape, size and thickness, and therefore the colorimetric dental films can be massively produced.