The invention discloses an end-type multi-stage grout stopping plug of a grouting anchor rod and a use method thereof. The end-type multi-stage grout stopping plug comprises a grout stopping plug body, a grout stopping cap and multi-stage grout stopping teeth, wherein the grout stopping cap is positioned at the end part of the grout stopping plug body; and the multi-stage grout stopping teeth are arranged on the outer surface of the grout stopping plug body. The invention has the advantages that in order that the friction force of the grout stopping plug at the end of the hollow grouting anchor rod and a drilling wall is increased, the smooth outer wall of the grout stopping plug is made into the multi-stage type similar to screw threads; and by full utilization of the characteristic of volume shrinkage of a rubber product after subjected to external pressure, the friction force of the grout stopping plug at the end of the hollow grouting anchor rod and the drilling wall is increased, no grout leakage and grout overflowing of the high-pressure hollow grouting anchor at the hole end in a grouting process can be ensured, and the purposes of pressurizing and grouting are achieved.