The invention provides a method utilizing an OPGW redundant cable to solve cross sensitivity existing in optical fiber Brillouin scattering monitoring, and belongs to the technical field of photoelectronic measurement. An optical fiber Brillouin scattering demodulation analyzer is connected with the optical fiber core of an OPGW. Only temperature changes can cause the Brillouin scattering frequency shift of the OPGW redundant cable on an electric power iron tower, and ice accretion, wind blowing and other external stress factors cannot cause the Brillouin scattering frequency shift. Temperature compensation is carried out on a Brillouin scattering monitor technology through the OPGW redundant cable, the temperature and strain information of the overhead OPGW is demodulated out, the running state of the OPGW is reflected through the temperature and strain information of the OPGW, and the failure point of the OPGW is located through a Brillouin scattering sensor technology. The temperature complementation is carried out by utilizing the OPGW redundant cable on the electric power iron tower, the temperature and the strain along the OPGW are monitored, and the on-line monitor of the running state of the OPGW can be achieved.