A nuclear fuel includes a volume of a nuclear fuel material defined by a surface, the nuclear fuel material including a plurality of grains, some of the plurality of grains having a characteristic length along at least one dimension that is smaller than or equal to a selected distance, wherein the selected distance is suitable for maintaining adequate diffusion of a fission product from a grain interior to a grain boundary in some of the grains, the nuclear fuel material including a boundary network configured to transport the fission product from at least one grain boundary of some of the grains to the surface of the volume of the nuclear fuel material.