The invention relates to an experimental determination method for simulation of cigarette combustion to generate ammonia. The method is characterized by: adopting a rapid temperature rise control device, taking a nitrogen-oxygen mixed gas or nitrogen as a carrier gas, and using a cambridge filter and an absorption liquid to trap ammonia in a pyrolysis product, then determining the content of NH3 in the cambridge filter and the absorption liquid by ion chromatography, thus realizing simulation of cigarette combustion smoking to generate NH3 and quantitative analysis thereof. Compared with previous methods for simulation of cigarette combustion smoking to generate NH3, the method provided by the invention has the advantages of large sample loading capacity, use of oxygen-nitrogen mixed gases with different ratios, rapid heating rate, no need for preparation of test cigarettes, and good experimental repeatability, etc., thus being suitable for research for rapid determination of NH3 precursors in flue gas.