The invention discloses a fibroin nanofiber haze protection product based on waste cocoon silk raw materials and relates to the technical field of utilization of the waste cocoon silk raw materials. A production process of the fibroin nanofiber haze protection product comprises the following steps: extracting fibroin from waste cocoon silks and preparing a fibroin membrane; preparing a functional fibroin spinning solution; preparing a multi-structure fibroin nanofiber membrane by nozzle-free high-speed electrostatic spinning; compounding a conventional textile fabric with the fibroin nanofiber membrane on line. According to the production process, a fibroin solution extracted from the waste cocoon silks is added with a functional material to prepare a composite spinning solution, and the waste silks in cocoon silk processing are deeply developed and utilized through the nozzle-free high-speed electrostatic spinning technology and the online compounding technology to research and develop the fibroin nanofiber membrane with multiple structures such as porous structures and bead structures; the specific surface area of fibers is enlarged, the adsorption capacity of the fibers on fine particles is increased and the breathability is improved by virtue of the porous structures and the bead structures; the product has a high-efficiency protection function on polluted air such as haze and PM2.5.