The invention discloses an electric vehicle direct-current charging pile capable of charging two vehicles simultaneously. The charging pile comprises an intelligent controller and two charging interface connectors. Direct-current charging interfaces of the two charging interface connectors are respectively connected with a direct-current contactor. Auxiliary power supply interfaces of the two charging interface connectors are respectively connected with an auxiliary control relay. A charging communication interface of the two charging interface connectors is connected with a communication interface of the intelligent controller through a switching relay, and the switching relay is used for switching connection according to the state of a controlling and determining interface of the corresponding charging interface connector. States of the auxiliary control relays, the direct-current contactors and the controlling and determining interfaces of the charging interface connectors are collected through driving in of the vehicles, and the on-off states of the corresponding auxiliary control relays and the direct-current contactors and the on-off states of CAN communication interface of the charging interface connectors and a CAN interface circuit of the intelligent controller are controlled through driving off of the vehicles. The electric vehicle direct-current charging pile is low in manufacturing cost, small in size, little in occupied space and high in comprehensive utilization rate, and meanwhile achieves intelligent and automated control.