The invention discloses an ultra violet radiation cross-linking polymeric material for 3D printing and a preparation method and a product thereof. Main components of the material contain, by weight, 100 parts of unsaturated resin and 0.5-5 parts of an UV cross-linking agent. In addition, the material also contains, by weight, 0.1-0.5 part of an antioxidant, 1-20 parts of a powder, 0-10 parts of a pigment and 0-5 parts of other auxiliary agents, which help enhance a printing effect of the material. With the addition of the UV cross-linking agent and by the utilization of ultraviolet irradiation, unsaturated resin is subjected to crosslinking after 3D printing extrusion so as to form a three-dimensional net structure. Heat resistance, resistance to chemical corrosion and mechanical strength of a moulding material are all raised to a large extent. Thus, unsaturated resin has a wider application prospect in 3D printing materials.