利索-全球专利检索

  1. 登录
  2. 注册
发明公开
CN104870453A 用于光电子应用的双核金属(I)络合物 有权 转让

用于光电子应用的双核金属(I)络合物
摘要：
本发明涉及一种式(A)的金属(I)络合物，其中M＝彼此独立地选自由Cu和Ag所组成的组；X＝彼此独立地选自由Cl、Br、I、CN、OCN、SCN、炔基及N3所组成的组；E∩D＝彼此独立地为双牙配位基，其中E＝RR'E*(如果E*＝N、P、As、Sb)或RE*(如果E*＝C*、O、S)，其中E*彼此独立地选自由N(其中N不是亚胺氮原子或N-杂芳环的一部分)、P、C*、O、S、As及Sb所组成的组，其中C*＝二价碳烯碳原子，并且R，R'＝彼此独立地选自以下组，该组包括：氢、卤素、及直接键结或经由氧(-OR)、氮(-NR2)、硅(-SiR3)或硫原子(-SR)键结的取代基、以及烷基、杂烷基、芳基、杂芳基、烯基、炔基或经取代的烷基、杂烷基、芳基、杂芳基及烯基(具有取代基，如卤素或氘、烷基、杂烷基、芳基、杂芳基)、及其它公知的供体及受体基团，以及CF3基团；D＝RR'D*(如果D*＝N、P、As、Sb)或RD*(如果D*＝C*、O、S)，其中D*彼此独立地选自由N(其中N不是亚胺氮原子或N-杂芳环的一部分)、P、C*、O、S、As及Sb所组成的组，其中C*＝二价碳烯碳原子，并且R，R'＝彼此独立地选自以下组，该组包括：氢、卤素、及直接键结或经由氧(-OR)、氮(-NR2)、硅(-SiR3)或硫原子(-SR)键结的取代基、以及烷基、杂烷基、芳基、杂芳基、烯基、炔基或经取代的烷基、杂烷基、芳基、杂芳基及烯基(具有取代基，如卤素或氘、烷基、杂烷基、芳基、杂芳基)、及其它公知的供体及受体基团，以及CF3基团；其中D和E是不同的；“∩”＝由Q、Y和Z组成的三部分单元，它们彼此键结并且彼此独立地选自以下组，该组包括：NR、O、S及PR以及烷基、杂烷基、芳基、杂芳基、烯基、炔基或经取代的烷基、杂烷基、芳基、杂芳基及烯基(具有取代基，如卤素或氘、烷基、杂烷基、芳基、杂芳基)及其它公知的供体及受体基团，如例如胺、羧酸根及其酯，以及CF3基团；本发明还涉及所述络合物在光电子器件中、特别是在OLED中的应用。
摘要（英）：

The invention relates to metal(I) complexes of the formula (A), in which M is selected independently of one another from the group consisting of Cu and Ag; X is selected independently of one another from the group consisting of Cl, Br, I, CN, OCN, SCN, alkinyl, and N3; E[intersect]D = independently of one another a bidental ligand, where E = RR'E* (if E* = N, P, As, Sb) or RE* (if E* = C*, O, S), where E* is selected independently of one another from the group consisting of N, wherein N is not an imine nitrogen atom or part of an N heteroaromatic ring, P, C*, O, S, As, and Sb, where C* = a divalent carbene carbon atom, and R and R' are selected independently of one another from the group consisting of hydrogen, halogen, and substituents, which are bound directly or via oxygen (-OR), nitrogen (-NR2), silicon (-SiR3) or sulfur atoms (-SR), and alkyl, heteroalkyl, aryl, heteroaryl, alkenyl, alkinyl groups or substituted alkyl, heteroalkyl, aryl, heteroaryl, and alkenyl groups (with substituents such as halogens or deuterium, alkyl groups, heteroalkyl, aryl, and heteroaryl groups), and additional generally known donor and acceptor groups and CF3 groups; D = RR'D* (if D* = N, P, As, Sb) or RD* (if D* = C*, O, S), where D* is selected independently of one another from the group consisting of N, wherein N is not an imine nitrogen atom or part of an N heteroaromatic ring, P, C*, O, S, As, and Sb, where C* = a divalent carbene carbon atom, and R and R' are selected independently of one another from the group consisting of hydrogen, halogen, and substituents, which are bound directly or via oxygen (-OR), nitrogen (-NR2), silicon (-SiR3) or sulfur atoms (-SR) and alkyl, heteroalkyl, aryl, heteroaryl, alkenyl, alkinyl groups or substituted alkyl, heteroalkyl, aryl, heteroaryl, and alkenyl groups (with substituents such as halogens or deuterium, alkyl groups, heteroalkyl, aryl, and heteroaryl groups), and additional generally known donor and acceptor groups and CF3 groups; wherein D and E are different; and "[intersect]" = a three-part unit consisting of Q, Y, and Z, which are bound to one another and are selected independently of one another from the group consisting of NR, O, S, and PR, and alkyl, heteroalkyl, aryl, heteroaryl, alkenyl, alkinyl groups or substituted alkyl, heteroalkyl, aryl, heteroaryl, and alkenyl groups with substituents such as halogens or deuterium, alkyl groups, heteroalkyl, aryl, heteroaryl, and additional generally known donor and acceptor groups, such as amines, carboxylates, the esters thereof, and CF3 groups for example. The invention also relates to the use of the metal(I) complexes in optoelectronic components, in particular OLEDs.

公开/授权文献
0/0