An optical film including cellulose acylate and a compound represented by General Formula (I) described below, a polarizing plate, and a liquid crystal display device; R1 and R3 represent hydrogen atoms, alkyl groups having 1 to 20 carbon atoms, cycloalkyl groups having 3 to 20 carbon atoms, alkenyl groups having 2 to 20 carbon atoms, or aromatic groups having 6 to 20 carbon atoms. R5 represents a hydrogen atom, an unsubstituted alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, or an aralkyl group represented by -L5-Ar5 (L5 represents an alkylene group having 1 to 20 carbon atoms and Ar5 represents an aromatic group having 6 to 20 carbon atoms). Here, the total of ring structures present in R1, R3, and R5 is one or two.