A lithium metal electrode is disclosed in this invention. The lithium metal electrode includes a lithium metal layer, a plurality of gate layers and a current collector layer having a plurality of holes. The gate layers are disposed corresponding to the holes. The lithium metal layer and the gate layers are disposed correspondingly. The lithium metal layer is insulated via the gate layers and/or the current collector layer before formation. While the gate layers are alloyed with the lithium ions from the media such as the electrolyte, the alloyed gate layers may provide the ionic access for the lithium metal layer so that the lithium metal layer may feedback the lithium ions back to the chemical system of the electricity supply system. Also, at the same time, the potentials of all the gate layers may be kept equally to the potential of the lithium metal layer.