The invention relates to a preparation method of a plasma-triggered fluorine-carbon oil-resistance and water-resistance paper. The method mainly relates to a fluorine-containing acrylic acid ester monomer dipping processing process and a plasma initiation processing process. The method comprises three preparation modes: 1) the paper is dipped in a fluorine-containing acrylic acid ester monomer for a certain time, then a plasma is used for initiating a grafting copolymerization reaction of the paper to prepare the fluorine-carbon oil-resistance and water-resistance paper; 2) the paper is performed with plasma initiation to generate a free radical, then is dipped in the fluorine-containing acrylic acid ester monomer, a grafting copolymerization reaction is carried out to prepare the fluorine-carbon oil-resistance and water-resistance paper; and 3) the paper is dipped in a fluorine-containing acrylic acid ester monomer for a certain time, is performed with the grafting copolymerization reaction through plasma initiation, then is dipped in the fluorine-containing acrylic acid ester monomer, the grafting copolymerization reaction is continuously generated to prepare the fluorine-carbon oil-resistance and water-resistance paper. The fluorine-carbon oil-resistance and water-resistance paper generates the contact angles of 132 DEG and 113 DEG respectively to water and to glycerin.