The present application relates to a distillation apparatus and a separation method, and according to the distillation apparatus and the separation method of the present application, it is possible to separate a material to be separated during the separation of a mixture of three or more components, for example, 2-ethylhexyl acrylate with high purity, and to achieve an object of saving energy during the separation and purification process of 2-ethylhexyl acrylate.