A cat-eye and embossed laser holographic transfer paperboard includes, in a successively laminated manner, a piece of paper, a glue layer, an UV coating layer and a cat-eye and embossed laser pattern layer. Because the UV coating layer has a moderate thickness, the cat-eye and embossed laser holographic transfer paperboard is not liable to generate cracks when being folded, and in addition, the UV coating layer is bond to the paper through the glue layer, so that the UV coating layer is attached to the paper well. The cat-eye and embossed laser holographic transfer paperboard is free of crack even being bent by 180 degrees, and is environment-friendly. The invention also provides a preparation method of the cat-eye and embossed laser holographic transfer paperboard.