The invention relates to molecular sieve preparation and aims to provide a solvent-free solid-phase synthesis method for a PERFER zeolite layered precursor.The solvent-free solid-phase synthesis method includes: disposing a silicon source, a fluorine source and organic amine in a mortar with grinding, transferring a ground mixture into a reaction kettle and crystallizing at 120-200 DEG C; subjecting a product to suction filtration and drying so as to obtain the PERFER zeolite layered precursor.The PERFER zeolite layered precursor maintains high degree of crystallinity and purity and has excellent catalytic reaction activity.The solvent-free solid-phase synthesis method for the PERFER zeolite layered precursor has the advantages that the whole preparation process is free of solvents, and accordingly unnecessary loss during preparation is reduced; inorganic materials adopted in preparation are environment friendly and low in price, so that the solvent-free solid-phase synthesis method is of great significance to actual chemical industry production fields; yield is increased, organic template reagents are reduced, and quite few organic template reagents are added into a reaction system; non-volatile ammonium fluoride substitutes for HF (hydrogen fluoride) completely, synthesis is facilitated and easily feasible, only simple grinding is involved in mixing and grinding time is short.