A wiring structure for a solar cell roof may include a moving glass slidably provided on a mechanism rail mounted on each of side frames that are disposed on both sides of a ceiling opening of a vehicle, and a fixed glass fixedly provided, a connection wire connected at a first end thereof to a solar cell included in the moving glass and connected at a second end thereof to a solar cell included in the fixed glass to allow electric current to flow therethrough, and a guide device provided on the side frame adjacent to the mechanism rail to be disposed in a longitudinal direction of the vehicle, and having a space to accommodate the connection wire therein, in which, when the moving glass is opened, the guide device accommodating the connection wire is restrained in movement in a transverse direction of the vehicle but is rotated only upwards.