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发明授权
CN105949471B 一种Zn(II)配位聚合物及其制备方法与应用 失效 - 权利终止

一种Zn(II)配位聚合物及其制备方法与应用
摘要：
本发明属于一种Zn(II)配位聚合物及其制备方法与应用；Zn(II)配位聚合物的化学式为：{Zn12(1，4‑NDC)12(TPY)12·2H2O}n；其中，1，4‑NDC＝1，4‑萘二甲酸，TPY＝4‑苯基‑2，2’：6’，2”‑三联吡啶；具有制备方法简单易操作，产品收率高，能够在130℃以下稳定，并且具有很强的三阶非线性光学反饱和吸收性能，纯材料的三阶非线性极化率χ(3)为6.46×10‑8esu，能够应用于光限幅和激光防护器件的优点。
摘要（英）：

The invention belongs to a Zn (II) coordination polymer as well as a preparation method and an application thereof. The chemical formula of the Zn (II) coordination polymer is [Zn 12(1,4-NDC )12(TPY )12*2H2O]n, wherein 1,4-NDC is 1,4-naphthalenedicarboxylic acid, TPY is 4-phenyl-2,2':6',2''-terpyridine. The Zn (II) coordination polymer as well as the preparation method and the application thereof have the advantages that the preparation method is simple and easy to operate, the product yield is high, the product can be stable at the temperature of 130 DEG C or lower and has high third-order nonlinear optical reverse saturable absorption performance, the third-order nonlinear susceptibility Chi<3> of a pure material is 6.46*10<-8> esu, and the Zn (II) coordination polymer can be applied to optical limiting and laser protection devices.

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