The invention relates to an oily high-temperature-resistant anti-bonding paint for steel-titanium and application thereof, belonging to the technical field of anti-bonding coatings for steel-titanium. The objective of the invention is to provide the oily high-temperature-resistant anti-bonding paint used in rolling of titanium pipes. The paint comprises, by weight, 50 to 150 parts of an oily film forming agent, 30 to 80 parts of tin powder, 250 to 350 parts of talcum powder and 400 to 450 parts of aluminum oxide powder. The anti-bonding paint provided by the invention coats steel equipment, a roller way or a capstan to form a good isolation layer, can guarantee that a titanium ingot does not bond with the roller or capstan of the steel equipment in the process of rolling or perforating at 900 DEG C, improves the precise dimension and surface quality of a product, enhances rolling yield and production efficiency of processing of titanium materials and reduces production cost.