The invention discloses a method for extracting and removing thiophene sulfide in gasoline through catalytic oxidation under visible light and belongs to the technical field of gasoline processing. According to the method disclosed by the invention, under the visible light, the thiophene sulfide is catalytically oxidized into thiophene sulfone by adopting a dyestuff sensitized photocatalyst through oxidization of an oxidant, and then the thiophene sulfone is extracted and separated through an extracting agent, so that the aim of removing the thiophene sulfone in the gasoline is realized. The dyestuff sensitized photocatalyst is prepared by a preparation method in Patent ZL201210553859.6. The dyestuff sensitized photocatalyst selected by the invention has a large specific surface area and relatively good dispersity; catalytic active sites are effectively exposed and the photocatalyst is not easy to lose; the utilization of a visible spectrum part in solar energy is remarkably improved. A desulfurization method provided by the invention is simple and feasible and low in cost, and can realize an effective removal effect on the thiophene sulfide in the gasoline.