The invention discloses an intrinsic super-hydrophobic ceramic coating and a preparing method thereof, and belongs to the technical field of metal base surface treatment. A titanium alloy or stainless steel serves as a base material, firstly, a double glow plasma permeability technology is adopted, lanthanide series metal serves as a double glow plasma permeability metal target material, a lanthanide metal coating is prepared on the surface of the base body material, and the plasma oxidization technology is adopted to convert the prepared lanthanide metal coating into a compact oxide ceramic coating. Due to the fact that in the plasma permeability and plasma oxidation process, the surface of the metal base body is continuously bombarded by Ar ions to form a certain micro rough structure, the prepared lanthanide metal oxide ceramic coating has a certain super-hydrophobic characteristic, and the contact angles are larger than 150 degrees. According to the provided method, the prepared super-hydrophobic ceramic coating has the stable environment adaptation, and compared with the super-hydrophobic surface prepared by the traditional technical means, the industrial service life of the coating is greatly prolonged.