The invention belongs to the technical field of surface treatment, and relates to a method for achieving controlled super-hydrophilic and super-hydrophobic inversion of a glass surface. The method is characterized in that controlled super-hydrophilic and super-hydrophobic inversion of the glass surface is achieved through growing different nano layers on the glass surface. According to the method for achieving controlled super-hydrophilic and super-hydrophobic inversion of the glass surface, controlled super-hydrophilic and super-hydrophobic inversion can be achieved through regulating and controlling a microstructure change of the material surface, and the defects of uncontrollable super-hydrophilic and super-hydrophobic inversion and unstable performance under light irradiation in the prior art are overcome.