Disclosed is a bioactive pillow with a health care function. The pillow comprises a pillow case and a pillow interior, the pillow case is filled with the pillow interior, the pillow interior comprises a pillow interior case and a filling arranged inside the pillow interior case, and the pillow interior case is made of activated carbon fiber materials with biological activity; one side of the pillow interior case is provided with a zipper; the filling is green tea with the biological activity; the pillow has the functions of super absorption of activated carbon fiber cloth, purification and bacteriostasis of probiotics in environment-friendly enzyme, and phlegm removal and arresting convulsion, brain activation and consciousness regaining, surrounding blood vessel expansion ofthe green tea and achieves the purpose of heath care function.