The invention relates to the field of a polymer composite material, in order to solve the problems of inferior fireproof safety, anti-ageing effect and inflammable property of most polymer materials. The invention provides a preparation method for an organic silicon and graphene oxide synergistic flame retardant polymer composite material. According to a method for respectively wrapping graphene oxide and organic silicon resin on the surface of a flammable polymer material, the excellent high temperature resistance and synergistic flame retardant effect of the graphene oxide and organic silicon resin are utilized to realize the efficient flame retardant fireproof property of the flammable polymer material, and meanwhile, the physical properties of the polymer material are effectively maintained.