The invention relates to the technical field of volatile organic compound waste gas pollution control, and in particular relates to a device for a procedure for preparing an adhesive by utilizing a volatile organic compound waste gas active adsorbent. The device is characterized by comprising a saturated steam heating kettle assembly, a hot air heating furnace assembly, an overheated sulfur steam buffering tank and a sulfur powder storage tank. Sulfur is heated to boiling point temperature or more to form overheated sulfur steam; then the overheated sulfur steam is rapidly cooled to 90 DEG C or lower to prepare a sulfur adhesive; the adhesive is provided for granulation of fly ash of a circulating fluidized bed coal-fired boiler; a step of preparing the overheated sulfur steam adopts a two-section heating manner of firstly heating to a fused state (a liquid phase) and then re-heating to the overheated sulfur steam (a gas phase); a sulfur polymer is obtained by quenching; a heating device, which is provided with a transpiration pipe and a circulating pipe for connecting a low-temperature section and a high-temperature section, is deigned by utilizing a transpiration principle, so as to finish material conveying.